Year-round record of bulk and size-segregated aerosol composition in central Antarctica (Concordia site) Part 2: Biogenic sulfur (sulfate and methanesulfonate) aerosol


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Rolf.Weller [ at ] awi.de

Abstract

Multiple year-round (2006-2015) records of the bulk and size-segregated composition of aerosol were obtained at 15 the inland site of Concordia located in East Antarctica. The well-marked maximum of non-sea-salt sulfate (nssSO4) in January (84 ± 25 ng m-3 against 4.4 ± 2.3 ng m-3 in July) is consistent with observations made at the coast (280 ± 78 ng m-3 in January against 16 ± 9 ng m-3 in July at Dumont d’Urville, for instance). In contrast, the well-marked maximum of MSA at the coast in January (60 ± 23 ng m-3 at Dumont d’Urville) is not observed at Concordia (4.6 ± 2.4 ng m-3 in January). Instead, the MSA level at Concordia peaks in October (5.6 ± 1.9 ng m-3) and March (13.2 ± 6.1 ng m-3). As a result, a surprisingly low MSA to nssSO4 ratio (RMSA) is observed at Concordia in mid-summer (0.05 ± 0.02 in January against 0.25 ± 0.09 in March). We find that the low value of RMSA in mid-summer at Concordia is mainly driven by a drop of MSA levels that takes place in submicron aerosol (0.3 μm diameter). The drop of MSA coincides with periods of high photochemical activity as indicated by high ozone levels, strongly suggesting the occurrence of an efficient chemical destruction of MSA over the Antarctic plateau in mid-summer. The relationship between MSA and nssSO4 levels is examined separately for each season and indicates that concentration of non-biogenic sulfate over the Antarctic plateau does not exceed 1 ng m-3 in fall and winter and remains below 5 ng m-3 in spring. This weak non-biogenic sulfate level is discussed in the light of radionuclides (210Pb, 10Be, and 7Be) also measured on bulk aerosol samples collected at Concordia. The findings highlight the complexity in using MSA in deep ice cores extracted from inland Antarctica as a proxy of past DMS emissions from the southern ocean.



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Article
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Primary Division
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Research Networks
Peer revision
Scopus/ISI peer-reviewed
Publication Status
Published
Eprint ID
44329
DOI 10.5194/acp-17-14055-2017

Cite as
Legrand, M. , Preunkert, S. , Weller, R. , Zipf, L. , Elsässer, C. , Merchel, S. , Rugel, G. and Wagenbach, D. (2017): Year-round record of bulk and size-segregated aerosol composition in central Antarctica (Concordia site) Part 2: Biogenic sulfur (sulfate and methanesulfonate) aerosol , Atmospheric Chemistry and Physics, 17 , pp. 14055-14073 . doi: 10.5194/acp-17-14055-2017


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